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AWWA WQTC64176

AWWA WQTC64176 The Effectiveness of Using ORP for Process Control of Manganese Oxidation/Removal

Conference Proceeding by American Water Works Association, 11/01/2006

Scribner, Thomas M.; Settle, H. Thomas, Jr.

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This slide presentation outlines a study on the effectiveness of using oxidation-reduction potential (ORP) for process control of manganese oxidation/removal. The drivers for this study included: theneed for a practical, accurate method forMn oxidation that was quality based,not just flow-based; a new remotely-operated microfiltrationmembrane facility was proposed; and,LT2ESWTR turb standards. Reasons for using ORP included: using KMnOsub4/sub as oxidant for soluble Mn (Mn,sup+2/sup);no drivers to consider alternatives ( ClOsub2/sub, etc.);low total organic carbon (TOC) ( 2 mg/L), TTHM 30, HAA5 20, 0 Color units;KMnOsub4/sub is a standard oxidation process thatshould be "measurable" with ORP;must use isolated feed point;proper downstream sampling point key; and,no other oxidants (i.e. Clsub2/sub) present. Implementation, process evolution, critical elements, ORP cleaning, and operation and maintenance are all outlined in the presentation. The summary of the study includes these points: flow-paced controls resulted in highly variableoxidation results, not qualitative;ORP provides a qualitative means for controllingfinished water Mn levels at finite levels;improves many elements of a surface water treatmentprocess (Clsub2/sub, disinfection byproducts (DBP), Turbidity, Filter Ops); and,maintains a constant oxidation potential (as measuredin mV) by dosing the correct amount of oxidant to meetthe required demand. Includes figures.

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